Tetrahedron

Reactions of perfluoroalkylcarbanions with sulphur

BL Dyatkin, SR Sterlin, LG Zhuravkova, BI Martynov…

Index: Dyatkin,B.L. et al. Tetrahedron, 1973 , vol. 29, p. 2759 - 2767

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Citation Number: 24

Abstract

The interaction of perfluoroalkylcarbanions generated (a) by the addition of the fluoride ion to fluoro-olefines and (b) from bis-perfluoroalkyl mercurials in the presence of the fluoride ion with elementary sulphur has been investigated and various transformations of the resulting perfluoroalkylmercaptide anions are shown.