Intermolecular hydroarylation of unactivated olefins catalyzed by homogeneous platinum complexes

AT Luedtke, KI Goldberg

Index: Luedtke, Avery T.; Goldberg, Karen I. Angewandte Chemie - International Edition, 2008 , vol. 47, # 40 p. 7694 - 7696

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Citation Number: 52

Abstract

The hydroarylation of olefins is a valuable CÀC bond forming reaction used to produce alkyl arenes.[1] Olefin hydroarylation can be catalyzed by Lewis acids, but such reactions proceed through a Friedel–Crafts type mechanism involving an intermediary carbocation. Thus, these reactions give predominantly Markovnikov products, and ortho, meta, and para selectivity is determined by the substituents on the aromatic ring. In contrast, the use of ...

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