Tetrahedron

Synthesis of substituted tetrahydron-1H-carbazol-1-one and analogs via PhI (OCOCF 3) 2-mediated oxidative C–C bond formation

H Shi, T Guo, D Zhang-Negrerie, Y Du, K Zhao

Index: Shi, Hao; Guo, Tianjian; Zhang-Negrerie, Daisy; Du, Yunfei; Zhao, Kang Tetrahedron, 2014 , vol. 70, # 17 p. 2753 - 2760

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Citation Number: 3

Abstract

Abstract A variety of tetrahydro-1H-carbazol-1-ones and analogs were conveniently synthesized from the reaction of the corresponding 2-(phenylamino) cyclohex-2-enone with hypervalent iodine reagent PhI (OCOCF 3) 2 (PIFA), through a direct intramolecular oxidative C (sp 2)–C (sp 2) bond formation. This approach realized the construction of the biologically important tetrahydro-1H-carbazol-1-one and tetrahydrocyclohepta [b] indol-6 ( ...

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