Enantioselective total syntheses of ropivacaine and its analogues
N Shankaraiah, RA Pilli, LS Santos
Index: Shankaraiah, Nagula; Pilli, Ronaldo Aloise; Santos, Leonardo S. Tetrahedron Letters, 2008 , vol. 49, # 34 p. 5098 - 5100
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Citation Number: 25
Abstract
An alternative asymmetric synthesis of ropivacaine and analogues employing the 'cation pool'strategy and host/guest supramolecular co-catalysis approach is presented. In this study, chiral auxiliaries, several soft nucleophiles as well as one-pot conditions for anodic oxidation, followed by nucleophilic addition, have been applied.
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