The design, synthesis and photochemical study of a biomimetic cyclodextrin model of Photoactive Yellow Protein (PYP)

C Loukou, P Changenet-Barret, MN Rager…

Index: Loukou, Christina; Changenet-Barret, Pascale; Rager, Marie-Noelle; Plaza, Pascal; Martin, Monique M.; Mallet, Jean-Maurice Organic and Biomolecular Chemistry, 2011 , vol. 9, # 7 p. 2209 - 2218

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Citation Number: 4

Abstract

The design, synthesis and study of the photophysical and photochemical properties of the first biomimetic cyclodextrin (CD) model of photoactive yellow protein (PYP) are described. This model bears a deprotonated trans-p-coumaric acid chromophore, covalently linked via a cysteine moiety to a permethylated 6-monoamino β-CD. NMR and UV/Visible spectroscopy studies showed the formation of strong self-inclusion complexes in water at ...

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