Synthesis and characterization of orthometalated rhodium (III) complexes containing substituted triazoles

JH Van Diemen, JG Haasnoot, R Hage…

Index: Diemen, John H. van; Haasnoot, Jaap G.; Hage, Ronald; Reedijk, Jan; Vos, Johannes G.; Wang, Renji Inorganic Chemistry, 1991 , vol. 30, p. 4038 - 4043

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Citation Number: 35

Abstract

L= 3-(pyridin-2-yl)-l, 2, 4-triazole (Ll), l-methyl-5-(pyridin-2-yl)-1, 2, 4-triazole (L2), l-methyl-3- (pyridin-2-yl)-l, 2, 4-triazole (L3). 4-methyl-3-(pyridin-2-yl)-1, 2, 4-triazole (L4), 3-methyl-5- (pyridin-2-yl)-1, 2, 4-triazole (L5), 3-(pyridin-2-yl)-5-phenyl-1, 2, 4-triazole (L6), 3-(pyridin-2- yl)-5-(3-nitrophenyl)-1.2, 4-triazole (L7), and 3-(pyridin-2-yl)-5-(2-thienyl)-l, 2, 4-triazole (L8) are reported. NMR spectroscopy has been used to characterize the coordination modes of ...