The synthesis and crystal structures of triphenyl (1, 2, 3-trimethylallyl) tin and triphenyl (1, 1, 2-trimethylallyl) tin

CM Van Zyl, JL McKeeby, PC Van Dort, EJ Larson…

Index: Zyl, Craig M. van; McKeeby, Jeffrey L.; Dort, Paul C. van; Larson, Erlund J.; Silver, Michael E.; Huffman, John C. Inorganica Chimica Acta, 1987 , vol. 133, p. 289 - 294

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Citation Number: 6

Abstract

Abstract In an attempt to isolate new allylating reagents, two new tin compounds, triphenyl (1, 2, 3-trimethylallyl) tin (3) and triphenyl (1, 1, 2-trimethylallyl) tin (4) have been prepared and their crystal structures determined. Both compounds are examples of σ-bound allyl complexes. However, the infrared spectra of both compounds do not show the absorptions characteristic of other σ-bound allyl complexes. The chemistry of these new compounds ...