Syntheses of Azobenzene Derivatives Having Fluoroalkyl Chain and Their Monomolecular Film Formation at the Air/Water Interface.

N Yoshino, M Kitamura, T Seto, Y Shibata…

Index: Yoshino, Norio; Kitamura, Mitsuharu; Seto, Tsuyoshi; Shibata, Yasuhiro; Abe, Masahiko; Ogino, Keizo Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 8 p. 2141 - 2144

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Citation Number: 33

Abstract

The compounds, 4-(nonafluorobutyl) aniline, 4-(tridecafluorohexyl) aniline, and 4- (heptadecafluorooctyl) aniline were prepared by the reaction of corresponding perfluoroalkyl iodide with 4-iodoaniline in the presence of copper bronze. Six azobenzene derivatives (4- (4-fluorophenylazo) phenol, F (C 6 H 4) N= N (C 6 H 4) OH (1)(C 6 H 4= p-phenylene), 4-(4- trifluoromethylphenylazo) phenol, CF 3 (C 6 H 4) N= N (C 6 H 4) OH (2), 4-(4- ...