Tetrahedron letters

A new facile diastereoconversion of 2-amino alcohols involving a novel cyclocarbamation

S Kano, T Yokomatsu, H Iwasawa, S Shibuya

Index: Kano, Shinzo; Yokomatsu, Tsutomu; Iwasawa, Haruo; Shibuya, Shiroshi Tetrahedron Letters, 1987 , vol. 28, # 50 p. 6331 - 6334

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Citation Number: 64

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Cyclization of N-Cbz-2-Amino alcohols with thionyl chloride gave oxazolidine-2-ones with inversion at the chiral center having a hydroxy group. Ring cleavage of oxazolidinone ring yielded the diastereoisomer of 2-amino alcohol used for cyclocarbamation. ... All new compounds ...

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