Electrophilic Bromination of Alkenes, Alkynes, and Aromatic Amines with Potassium Bromide/Orthoperiodic Acid under Mild Conditions

A Khazaei, MA Zolfigol, E Kolvari, N Koukabi…

Index: Khazaei, Ardeshir; Zolfigol, Mohammad Ali; Kolvari, Eskandar; Koukabi, Nadiya; Soltani, Hamid; Komaki, Fatemeh Synthesis, 2009 , # 21 p. 3672 - 3676

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Citation Number: 16

Abstract

Abstract Bromination of alkenes, alkynes, and aromatic amines has efficiently been carried out at room temperature in short reaction times using potassium bromide/orthoperiodic acid in dichloromethane-water (1: 1) to prepare the corresponding bromo compounds with excellent yields.

The Activation of Aromatic Halogen by Ortho Ammonium Salt Groups

[Emerson; Dorf; Deutschman Journal of the American Chemical Society, 1940 , vol. 62, p. 2159]

Carbanionisch induzierte [1, 3]??Wanderungen π??und koordinativ ungesättigter Gruppen

[Hellwinkel, Dieter; Laemmerzahl, Frank; Hofmann, Gunter Chemische Berichte, 1983 , vol. 116, # 10 p. 3375 - 3405]