Partial hydrolysis of acyl 1, 6-anhydro-β-D-glucopyranose

Š Kučár, J Zámocký, J Zemek, D Anderle…

Index: Kucar, Stefan; Zamocky, Juraj; Zemek, Juraj; Anderle, Dusan; Matulova, Maria Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 8 p. 1780 - 1787

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Citation Number: 12

Abstract

Abstract Partial hydrolysis of per-O-acetyl-and per-O-benzoyl derivatives of 1, 6-anhydro-β-D- glucopyranose with methanolic hydrogen chloride and hydrazine hydrate was investigated. The acyl group at C (3) is of substantial influence on the course of hydrolysis. The esterified hydroxyl group at C (3) was found to be most stable on acid hydrolysis with methanolic hydrogen chloride when compared with that at C (2), or C (4); on the other hand, this ester ...