Tetrahedron letters

Preparation and use of lithiated glycals: vinylic deprotonation versus tin-lithium exchange from 1-tributylstannyl glycals 1

P Lesimple, JM Beau, G Jaurand, P Sinaÿ

Index: Lesimple, Patrick; Beau, Jean-Marie; Jaurand, Guy; Sinay, Pierre Tetrahedron Letters, 1986 , vol. 27, # 51 p. 6201 - 6204

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Citation Number: 93

Abstract

Abstract Methods for preparing glycals lithiated at the C-1 atom by either direct vinylic deprotonation or by tin-lithium exchange from the corresponding 1-tri-n-butylstannyl glycals are described. Alkylation of these lithiated anions with various electrophiles leads to ...

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