Enthalpy–Entropy Compensation Combined with Cohesive Free??Energy Densities for Tuning the Melting Temperatures of Cyanobiphenyl Derivatives

…, D Emery, J Mareda, S Floquet, C Piguet

Index: Dutronc, Thibault; Terazzi, Emmanuel; Guenee, Laure; Buchwalder, Kerry-Lee; Spoerri, Aurore; Emery, Daniel; Mareda, Jiri; Floquet, Sebastien; Piguet, Claude Chemistry - A European Journal, 2013 , vol. 19, # 26 p. 8447 - 8456

Full Text: HTML

Citation Number: 9

Abstract

Abstract This work illustrates how minor structural perturbations produced by methylation of 4′-(dodecyloxy)-4-cyanobiphenyl leads to enthalpy–entropy compensation for their melting processes, a trend which can be analyzed within the frame of a simple intermolecular cohesive model. The transformation of the melting thermodynamic parameters collected at variable temperatures into cohesive free-energy densities expressed at a common ...

Related Articles:

Dimerization of dendrimeric lanthanide complexes: thermodynamic, thermal, and liquid-crystalline properties

[Jensen, Thomas Binderup; Terazzi, Emmanuel; Buchwalder, Kerry-Lee; Guenee, Laure; Nozary, Homayoun; Schenk, Kurt; Heinrich, Benoit; Donnio, Bertrand; Guillon, Daniel; Piguet, Claude Inorganic Chemistry, 2010 , vol. 49, # 18 p. 8601 - 8619]

Structure–activity relationships of arylbenzofuran H 3 receptor antagonists

[Gfesser, Gregory A.; Faghih, Ramin; Bennani, Youssef L.; Curtis, Michael P.; Esbenshade, Timothy A.; Hancock, Arthur A.; Cowart, Marlon D. Bioorganic and Medicinal Chemistry Letters, 2005 , vol. 15, # 10 p. 2559 - 2563]

More Articles...