Organic letters

Calix [4] arenes linked to multiple bidentate N-donors: potential ligands for synthetic modeling of multinuclear metalloenzymes

DJE Spencer, BJ Johnson, BJ Johnson…

Index: Spencer, Douglas J. E.; Johnson, Bryan J.; Johnson, Brian J.; Tolman, William B. Organic Letters, 2002 , vol. 4, # 8 p. 1391 - 1393

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Citation Number: 23

Abstract

A series of calix [4] arenes incorporating three or four bidentate diamines or pyridylamines attached at the “upper rim” were synthesized via practical protocols. Proof of structure was obtained in one instance by X-ray crystallography. These molecules are designed for general use as ligands for the preparation of multinuclear active site models of metalloenzymes.

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