Vinyl Derivatives of Metals. XIII. Some Addition Reactions of Triethylperfluorovinylsilane: The F19 Nuclear Resonance Spectra of the Triethylperfluorovinyl Derivatives …

D Seyferth, T Wada, GE Maciel

Index: Seyferth, D.; Wada, T.; Maciel, G. A. Inorganic Chemistry, 1962 , vol. 1, p. 232 - 235

Full Text: HTML

Citation Number: 17

Abstract

The reactions of triethylperfluorovinylsilane with bromine, hydrogen bromide, bromotrichloromethane, carbon tetrabromide, and trifluoroiodomethane result in (CzH;) &KFBrCFzBr,(C2H6) 3SiCFHCF2Br,(C2H5) &XCFBr-CF&C13,(C2H6) &iCFBrCF2CBr3, and (C2H6) 3SiCFICF2CF3, respectively. The structures of the hydrogen bromide and bromotrichloromethane adducts were confirmed using nmr spectroscopy. Chlorine does ...