Reverse prenyl transferases exhibit poor facial discrimination in the biosynthesis of paraherquamide A, brevianamide A, and austamide
EM Stocking, RM Williams…
Index: Gorst-Allman, Charles P.; Steyn, Pieter S. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 163 - 168
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Citation Number: 37
Abstract
... phosphorylated end, but at C-3, which bears the geminal methyl groups; this is formally an S N 2 ... in 1971 when deoxybrevianamide E (20) was isolated from the austamide-producing (21) cultures of Aspergillus ustus by Steyn. ... 13. It is of further significance that Gorst-Allman et al. ...
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