The Journal of organic chemistry

2, 2′-Biphenols via Protecting Group-Free Thermal or Microwave-Accelerated Suzuki–Miyaura Coupling in Water

B Schmidt, M Riemer, M Karras

Index: Schmidt, Bernd; Riemer, Martin; Karras, Manfred Journal of Organic Chemistry, 2013 , vol. 78, # 17 p. 8680 - 8688

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Citation Number: 15

Abstract

User-friendly protocols for the protecting group-free synthesis of 2, 2′-biphenols via Suzuki– Miyaura coupling of o-halophenols and o-boronophenol are presented. The reactions proceed in water in the presence of simple additives such as K2CO3, KOH, KF, or TBAF and with commercially available Pd/C as precatalyst. Expensive or laboriously synthesized ligands or other additives are not required. In the case of bromophenols, efficient rate ...

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