Derives N-Germanies De La 2, 4, 6-Trifluoroaniline: Germylamines, Germa-Imine, Cyclodigermazane

M Riviere-baudet, F El Baz, J Satge…

Index: Riviere-Baudet, Monique; El Baz, Fatima; Satge, Jaques; Khallaayoun, Abdelhay; Ahra, Mohamed Phosphorus, Sulfur and Silicon and Related Elements, 1996 , vol. 112, # 1-4 p. 203 - 217

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Citation Number: 6

Abstract

Abstract Germyl derivatives of N-2, 4, 6-trifluoroaniline were synthesized either by dehydrohalogenation between halogermanes and 2, 4, 6-trifluoroaniline over DBU (1, 8- diazabicyclo [5.4. 0] undec-7-ene) or by elimination between halogermanes and 2, 4, 6- trifluoroanilinolithium. Dimesitylfluorogermyl N-2, 4, 6-trifluoroanilino-lithium stabilized by THF slowly eliminated lithium fluoride leading to 2, 4 (2, 4, 6-trifluorophenyl)-1, 3- ...