Synthesis and characterization of pyridinyldisiloxanes and their bis-N-oxides

M Zeldin, JM Xu, CX Tian

Index: Zeldin, Martel; Xu, Jian-Min; Tian, Cheng-Xiang Journal of Organometallic Chemistry, 1987 , vol. 326, p. 341 - 346

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Citation Number: 12

Abstract

Abstract 2-(A) and 3-dimethylchlorosilylpyridine (B) were synthesized by reaction of the corresponding lithiopyridines with dimethyldichlorosilane at− 76 C. The products were hydrolyzed in aqueous ammonia at room temperature to give the respective disiloxanes (C and D) which are stable, colorless distillable liquids. The dimers were characterized by IR, 1 H NMR and MS. The principal by-products of the syntheses were the bis-substituted ...