A Rapid and Simple Method for Quantitative Aziridination from Aminobrominated Derivatives of Olefins under Solvent??free and Mild Conditions

J Wei, Z Chen, Y Gao, P Zhang, C Wang…

Index: Wei, Junfa; Chen, Zhanguo; Gao, Yanni; Zhang, Peng; Wang, Chuanning; Zhao, Pengfei; Wang, Yun; Shi, Xianying Chinese Journal of Chemistry, 2012 , vol. 30, # 2 p. 391 - 399

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Citation Number: 3

Abstract

Abstract The urea-catalyzed aziridination of 1, 2-vicinal haloamines derived from aminohalogenation of olefins has been developed. This rapid and simple method was carried out by simply grinding the solid mixture of the substrate, K 2 CO 3 and catalytic amount of urea at room temperature in air. The reaction provides a protocol for quantitative preparation of aziridines in a large scope of aminohalogenated derivatives of olefins ...

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