The Journal of Organic Chemistry

Chemistry of nitrogen radicals. VI. The free-radical addition of dialkyl-N-chloramines to substituted olefins

RS Neale, NL Marcus

Index: Neale,R.S.; Marcus,N.L. Journal of Organic Chemistry, 1967 , vol. 32, p. 3273 - 3284

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Citation Number: 22

Abstract

Results Vinyl Compounds (Table I).-The reactions realized between simple dialkylchloramines and substituted olefins R'CH= CXR2 can be conveniently grouped into those involving either vinyl or allyl (X= CH2Y) substrates. Most of the reactions were carried out in 4 M sulfuric acid-acetic acid under the conditions employed previously'with unsubstituted hydrocarbons, although some reactions in other acidic media are described ...