Chemical Communications

Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes

MD Greenhalgh, SP Thomas

Index: Greenhalgh, Mark D.; Thomas, Stephen P. Chemical Communications, 2013 , vol. 49, # 95 p. 11230 - 11232

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Citation Number: 43

Abstract

The highly chemo-, regio-, and stereoselective synthesis of alkyl-and vinyl boronic esters with good functional group tolerance has been developed using in situ activation of a bench- stable iron (II) pre-catalyst and pinacolborane (16 examples, 45–95% yield, TOF up to 30000 mol h− 1). The first iron-catalysed alkene hydrogermylation is also reported.

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