Kinetic studies of hydrazine and 2??hydroxyethylhydrazine alkylation by 2??chloroethanol: Influence of a strong base in the medium

V Goutelle, V Pasquet, J Stephan…

Index: Goutelle; Pasquet; Stephan; Bougrine; Delalu International Journal of Chemical Kinetics, 2009 , vol. 41, # 6 p. 382 - 393

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Citation Number: 4

Abstract

Abstract To optimize yields, the study of reaction kinetics related to the synthesis of 2- hydroxyethylhydrazine (HEH) obtained from the alkylation of N 2 H 4 by 2-chloroethanol (CletOH) was carried out with and without sodium hydroxide. In both cases, the main reaction of HEH formation was followed by a consecutive, parallel reaction of HEH alkylation (or dialkylation of N 2 H 4), leading to the formation of two isomers: 1, 1-di (hydroxyethyl) ...

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