X-ray and neutron-diffraction studies of the crystal structures of the dicesium lithium hexacyanometallates of manganese (III) and chromium (III)

BM Chadwick, DW Jones, HJ Wilde…

Index: Chadwick, B. M.; Jones, D. W.; Wilde, H. J.; Yerkess, J. Journal of Crystallographic and Spectroscopic Research, 1988 , vol. 18, # 1 p. 55 - 66

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Citation Number: 5

Abstract

Abstract Crystallographic examination of samples of Cs 2 Li [M III (CN) 6](M III= Mn, Cr), prepared by an improved route, establishes the unit cells as very closely approximating to face-centered cubic with lattice constants a= 10.64 (1)(M III= Mn) and 10.75 (1) Å (M III= Cr). Although a few weak non-face-centered cubic reflections and splittings were detected by powder neutron diffraction, refinement in Fm3m was as good as in primitive cubic or ...