Tetrahedron letters

Ethylmagnesium bromide mediated desulfinylation of α-halo-β-ketosulfoxides giving α-haloketones, and trapping of the magnesium enolate intermediate

T Satoh, K Onda, N Itoh, K Yamakawa

Index: Satoh, Tsuyoshi; Onda, Ken-ichi; Itoh, Norifumi; Yamakawa, Koji Tetrahedron Letters, 1991 , vol. 32, # 40 p. 5599 - 5600

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Citation Number: 12

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Treatment of α-halo-β-ketosulfoxides with EtMgBr gives α-haloketones in high yields after protonation of the magnesium enolates. Trapping of the magnesium enolates with various electrophiles is also carried out. ... Cookies are used by this site. To decline or learn more, visit our ...

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