Preparation of S-Vinylsulfilimines

T Yamamoto, M Kakimoto, M Okawara

Index: Yamamoto,T. et al. Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 841 - 845

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Citation Number: 14

Abstract

For the preparation of S-vinylsulfilimines (1), mainly S-phenyl-N-tosyl-S-vinylsulfilimine, three routes were examined, viz.,(A) the reaction of vinyl sulfide with chloramine T,(B) that of 2-haloethyl phenyl sulfide with chloramine T followed by dehydrohalogenation, and (C) that of 2-hydroxyethyl sulfide with chloramine T followed by acetylation of the hydroxyl group and deacetoxylation. Route A has disadvantages of troublesome preparation of vinyl sulfides ...