Steroids

Studies on anabolic steroids. 9. Tertiary sulfates of anabolic 17α-methyl steroids: synthesis and rearrangement

H Bi, R Massé, G Just

Index: Bi, Honggang; Masse, Robert; Just, George Steroids, 1992 , vol. 57, # 7 p. 306 - 312

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Citation Number: 21

Abstract

Abstract A simple and convenient method has been developed to prepare sulfates of anabolic 17β-hydroxy-17α-methyl steroids. The sulfates of methandienone, 17α- methyltestosterone, mestanolone, oxandrolone, and stanozolol were prepared. Different A- ring functions were not affected under the sulfation condition. The buffered hydrolyses of these sulfates provided the 17-epimers of the original steroids and 17, 17-dimethyl-18-nor ...