Direct Formation of (Haloaryl) copper Nucleophiles from Haloiodobenzenes and Active Copper

…, DR Pfennig, SD Suchan, TA Donovan Jr…

Index: Ebert, Greg W.; Pfennig, Deborah R.; Suchan, Scott D.; Donovan, Thomas A.; Aouad, Emmanuel; et al. Journal of Organic Chemistry, 1995 , vol. 60, # 8 p. 2361 - 2364

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Citation Number: 12

Abstract

(0-Halopheny1)-,(m-halophenyb, and (p-halopheny1) copper reagents have been formed in moderate to high yields at room temperature from active copper and the corresponding haloiodobenzenes. These reagents have been cross-coupled with a variety of alkyl and acyl halides to produce the respective haloarenes and haloaryl ketones. Remarkably,(0- fluoropheny1)-and (0-chloropheny1)-copper are produced in good yields by this ...

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