π??Conjugated Ligand Polymers Entwined around Copper Centres

PL Vidal, B Divisia??Blohorn, G Bidan…

Index: Vidal, Pierre-Louis; Divisia-Blohorn, Bernadette; Bidan, Gerard; Hazemann, Jean-Louis; Kern, Jean-Marc; Sauvage, Jean-Pierre Chemistry - A European Journal, 2000 , vol. 6, # 9 p. 1663 - 1673

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Citation Number: 43

Abstract

Abstract We describe conjugated polymers entwined around Cu I with alternating α- quaterthienyl (poly [Cu (T 2) 2]) or 3′, 4′, 3′′′′, 4′′′′-tetrahexyl-α-sexythienyl (poly [Cu (T 3) 2]) moieties and 1, 10-phenanthroline complexing sites. Our strategy is to synthesise the 2, 9-bis (oligothienyl)-1, 10-phenanthroline precursors, then to assemble these ligands by means of Cu I templating followed by electropolymerisation. Poly [Cu (T 2 ...