Palladium-catalysed hydrostannylations of 1-bromoalkynes. A practical synthesis of (E)-1-stannylalk-1-enes

CDJ Boden, G Pattenden, T Ye

Index: Boden, Christopher D. J.; Pattenden, Gerald; Ye, Tao Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 20 p. 2417 - 2419

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Citation Number: 74

Abstract

A practical synthesis of (E)-1-stannylalk-1-enes ... Christopher DJ Boden, Gerald Pattenden * and Tao Ye ... Chemistry Department, Nottingham University, Nottingham NG7 2RD, UK ... A practical synthesis of (4-1-stannylalk-1 -enes containing a range of oxygen and nitrogen functionality is highlighted, involving hydrostannylation followed by palladium- catalysed carbon-bromine bond cleavage reactions of 1- bromoal kynes. ... Vinylstannanes are pivotal ...