Unique Molecular Structures of Tungsten Phenoxides.

…, H Yasuda, Y Nakayama, A Nakamura

Index: Kanehisa, Nobuko; Kai, Yasushi; Kasai, Nobutami; Yasuda, Hajime; Nakayama, Yuushou; Nakamura, Akira Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 5 p. 1197 - 1201

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Citation Number: 17

Abstract

As a series of structural chemistry of early transition metal-phenoxides, the molecular structures of WCl 5 [2, 6-(CH 3) 2 C 6 H 3 O](1) and WCl 4 [2, 6-(CH 3) 2 C 6 H 3 O] 2 (2) have been determined by an X-ray diffraction method. Crystal data: 1; orthorhombic, space group Cmcm, a= 7.979 (3), b= 17.094 (4), c= 12.536 (2) Å, V= 1709.7 (8) Å 3, Z= 4, D c= 2.412 g cm− 3, 2; monoclinic, space group C2/m, a= 17.615 (4), b= 7.188 (2), c= 8.396 (2) ...

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