Journal of organometallic chemistry

1 H NMR evidence for the formation of vinyllead triacetates. The reactions of vinylmercury, vinyltin, and vinylboronic acids with lead tetraacetate

CJ Parkinson, MJ Stoermer

Index: Parkinson, Christopher J.; Stoermer, Martin J. Journal of Organometallic Chemistry, 1996 , vol. 507, # 1-2 p. 207 - 214

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Citation Number: 5

Abstract

Vinylmercury compounds, vinylboronic acids and vinylstannanes undergo rapid metal-lead exchange with lead tetraacetate in deuterochloroform to generate vinyllead triacetates, which have been characterised by their 1H 1H and 207Pb 1H coupling constants. In addition, a number of divinyl and mixed aryl-vinyllead dicarboxylates have been prepared via boron-lead exchange.

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