On the conjugative isomerizations of. beta.,. gamma.-unsaturated esters. Stereochemical generalizations and predictions for 1, 3-prototropic shifts under basic …

…, R Bohlmann, LM Harwood, JI Seeman

Index: Alcock, Simon G.; Baldwin, Jack E.; Bohlmann, Rolf; Harwood, Laurence M.; Seeman, Jeffrey I. Journal of Organic Chemistry, 1985 , vol. 50, # 19 p. 3526 - 3535

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Citation Number: 37

Abstract

Results Kinetic deconjugation of a, p-unsaturated esters to their P, y-unsaturated counterparts involves the formation of a molar equivalent of an enolate anion which is subsequently quenched to the corresponding P, y-unsaturated e~ ter.~-~ The inverse, kinetic conjugative process also formally involves an anionic intermediate. For both of these counterpart isomerizations to be experimentally attainable they must pass through ...