Probing the Role of Polyphenol Oxidation in Mediating Insect-Pathogen Interactions. Galloyl-Derived Electrophilic Traps for the Lymantria d ispar Nuclear …
KS Feldman, A Sambandam, KE Bowers…
Index: Feldman, Ken S.; Sambandam, Aruna; Bowers, Katherine E.; Appel, Heidi M. Journal of Organic Chemistry, 1999 , vol. 64, # 16 p. 5794 - 5803
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Citation Number: 18
Abstract
Galloyl-derived orthoquinone probes have been designed, synthesized, and utilized in an ongoing study of insect-pathogen interactions. A stable galloyl-derived orthoquinone O- methyl ether modified with both acidic and fluorescent appendages was successful in trapping the model nucleophile cysteine, a test protein bearing a single cysteine residue, and the viral occlusion body matrix protein polyhedrin from Lymantria dispar nuclear ...
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