Cross-linked normal hexagonal and bicontinuous cubic assemblies via polymerizable gemini amphiphiles

BA Pindzola, J Jin, DL Gin

Index: Pindzola, Brad A.; Jin, Jizhu; Gin, Douglas L. Journal of the American Chemical Society, 2003 , vol. 125, # 10 p. 2940 - 2949

Full Text: HTML

Citation Number: 91

Abstract

The synthesis and lyotropic liquid-crystalline (LLC) phase behavior of a homologous series of intrinsically cross-linkable gemini surfactants are described. These novel bis (alkyl-1, 3- diene)-based phosphonium gemini amphiphiles exhibit “normal” hexagonal (HI), Type I bicontinuous cubic (QI), and lamellar (Lα) phases in water, and can be photocross-linked with retention of phase architecture in each case. On the basis of their locations on the ...

Related Articles:

Reactions of Difluorosilylene with Amines, Phosphines and Halomethanes The First Evidence of the Insertion of Difluorosilylene into Tetrafluorosilane

[Chang, Chih-Wei; Liu, Chao-Shiuan; Lee, Chi-Young Journal of the Chinese Chemical Society, 1999 , vol. 46, # 3 p. 445 - 452]

Reactions of hexafluoroacetone with phosphorus (III) compounds

[Kischkel, Helmut; Roeschenthaler, Gerd-Volker Journal of Fluorine Chemistry, 1985 , vol. 29, p. 94]

Principles of Phosphorus Chemistry: Molecular States of Phosphorus Compounds-A Report on Gasphase Investigations 1-3

[Bock, Hans Phosphorus, Sulfur and Silicon and the Related Elements, 1990 , vol. 49/50, p. 3 - 53]

More Articles...