Bulletin of the Chemical Society of Japan

Solvent and Steric Effects on the Solvolysis of Polyvinylsulfonic Acid Esters

S Yoshikawa, OK Kim, T Hori

Index: Yoshikawa,S. et al. Bulletin of the Chemical Society of Japan, 1966 , vol. 39, p. 1937 - 1941

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Citation Number: 2

Abstract

The solvolysis of ethanesulfonic acid esters followed closely first-order kinetics, while the case of polyvinylsulfonic acid esters gave strongly-curved first-order plots according to the solvent composition. With a high acetone content, the solvolysis rates of polymeric sulfonic esters decreased gradually with the lapse of time, while in a high water content, the solvolysis was suppressed at the beginning of the reaction but was accelerated ...