Fluorination with ionic liquid EMIMF (HF) 2.3 as mild HF source

H Yoshino, K Matsumoto, R Hagiwara, Y Ito…

Index: Yoshino, Hideaki; Matsumoto, Kazuhiko; Hagiwara, Rika; Ito, Yasuhiko; Oshima, Koichiro; Matsubara, Seijiro Journal of Fluorine Chemistry, 2006 , vol. 127, # 1 p. 29 - 35

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Citation Number: 29

Abstract

Hydrogen fluoride is a basic fluorinating reagent, but handling it is difficult. For this reason, some modified fluorinating reagents such as HF-pyridine, Et3N-HF, and poly (hydrogen fluoride) complex have been developed. Those reagents, however, still require aqueous work-up procedures which generate hydrogen fluoride. Recently, ionic liquids have received much attention because of the ease in handling them and the possibility of non-aqueous ...