Journal of molecular structure

Synthesis, structure and photophysical properties of complexes [1-(9-anthracylmethyl)-3-alkylimidazol-2-ylidene] 2 Pt (C CPh) 2

QX Liu, FB Xu, QS Li, HB Song, ZZ Zhang

Index: Liu, Qing-Xiang; Xu, Feng-Bo; Li, Qing-Shan; Song, Hai-Bin; Zhang, Zheng-Zhi Journal of Molecular Structure, 2004 , vol. 697, # 1-3 p. 131 - 135

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Citation Number: 2

Abstract

1-(9-Anthracenylmethyl)-3-octylimidazolium chloride (1a) or 1-(9-anthracenylmethyl)-3- ethylimidazolium iodide (1b) was treated with (cod) Pt (C CPh) 2 to afford the luminescent complexes [1-(9-anthracylmethyl)-3-alkylimidazol-2-ylidene] 2Pt (C CPh) 2 (2a: alkyl C8H17, 2b: alkyl C2H5). Complex 2a crystallizes in triclinic system, space group Pı̄, a= 8.615 (3), b= 13.839 (5), c= 13.870 (5) Å, α= 85.275 (6)°, β= 84.062 (6)°, γ= 72.901 (6)°, Z= ...