A Convenient Two-Pot Conversion of Aldehydes to Sec-Alkyl Primary Amines: Reactions of α-(Benzotriazol-1-yl) Alkyliminophosphoranes with Organocerium (III) Or …

AR Katritzky, R Mazurkiewicz, CV Stevens…

Index: Katritzky; Mazurkiewicz; Stevens; Gordeev; Steel Synthetic Communications, 1994 , vol. 24, # 20 p. 2955 - 2972

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Citation Number: 15

Abstract

Abstract 1-(a-Phosphoroylideneaminoalky1) benzotriazoles reacted with organocerium (III) dichlorides or Grignard reagents to produce N-(sec-alkyl) iminophosphoranes, which were hydrolyzed to sec-alkyl primary amines in good overall yields. This sequence provides a convenient two-pot transformation of aldehydes to sec-alkyl primary amines.

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