Osmium-catalyzed vicinal oxyamination of olefins by N-chloro-N-argentocarbamates

E Herranz, SA Biller, KB Sharpless

Index: Herranz,E. et al. Journal of the American Chemical Society, 1978 , vol. 100, p. 3596 - 3598

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Citation Number: 70

Abstract

The incident irradiance of photons (“white light”) focused on the Pt-Chl a electrode was 1.74 W cm-2. An energy storage efficiency of 0.04%, given by the ratio of the rate of chemical free energy stored (in the form of H2 and 0 2) and the incident irradiance, was thus obtained for the observed rate mol/h) of water photolysis employing lOI7 Chl a molecules. We estimate that< 1% of the light was effectively engaged in the photoreaction. 13 It seems reasonable ...

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