Catalytic and highly regiospecific carbon–carbon bond formation at α-position of Michael acceptor by palladium complex

…, JC Park, CS Cho, SC Shim, Y Yamamoto

Index: Shim, Jae-Goo; Jong, Chul Park; Chan, Sik Cho; Sang, Chul Shim; Yamamoto, Yoshinori Chemical Communications, 2002 , # 8 p. 852 - 853

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Citation Number: 9

Abstract

Recently, Trost and Yamamoto have developed new methods affording two new carbon–carbon bonds successively at the β- and α-positions of Michael acceptors via the amphiphilic reaction of activated olefins and bis-π-allylpalladium complex (or its unsymmetric and functionalized derivative) (route b, Scheme 1). 2 These results encouraged us to study highly regiospecific carbon–carbon bond formation at the α-position of activated olefins (route c, Scheme 1). 3 ...