Novel Synthesis of 2-Phosphinoylphospholane 1-Oxide Derivatives.

Y Miyamoto, M Yamashita, T Oshikawa

Index: Miyamoto, Yasushi; Yamashita, Mitsuji; Oshikawa, Tatsuo Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 7 p. 2004 - 2006

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Abstract

Reactions of 2-phospholene 1-oxides with N-bromoacetamide in aqueous organic solvent produced 2-bromo-3-hydroxyphospholane 1-oxides, which reacted with sodium salts of dialkyl phosphonates to afford novel 2-phosphinoylphospholane 1-oxide derivatives. A 4- phosphin-oyl-2-phospholene derivative was also prepared.