Tetrahedron

4-Hydroxy-3-nitrosobenzamide and its ferrous chelate from Streptomyces murayamaensis

MC Cone, CR Melville, JR Carney, MP Gore, SJ Gould

Index: Cone, Martha C.; Melville, Chris R.; Carney, John R.; Gore, Makarand P.; Gould, Steven J. Tetrahedron, 1995 , vol. 51, # 11 p. 3095 - 3102

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Citation Number: 20

Abstract

Two new colored metabolites of Streptomyces murayamaensis have been isolated and characterized as 4-hydroxy-3-nitrosobenzamide and its ferrous chelate. These structures have been confirmed by synthesis via a modified Baudisch reaction. A sample of 3-amino-4- hydroxy [2-2H] benzoic acid was fed to S. murayamaensis, affording a sample of the 4- hydroxy-3-nitrosobenzamide ferrous chelate deuterated at C-2 (28.5% enrichment, 3.2% ...