The Journal of Physical Chemistry A

Investigation of the Thermal and Photochemical Reactions of Ozone with 2, 3-Dimethyl-2-butene

BE Coleman, BS Ault

Index: Coleman, Bridgett E.; Ault, Bruce S. Journal of Physical Chemistry A, 2010 , vol. 114, # 48 p. 12667 - 12674

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Citation Number: 11

Abstract

The matrix isolation technique, combined with infrared spectroscopy and twin jet codeposition, has been used to characterize intermediates formed during the ozonolysis of 2, 3-dimethyl-2-butene (DMB). Absorptions of early intermediates in the twin jet experiments grew up to 200% upon annealing to 35 K. A number of these absorptions have been assigned to the elusive Criegee intermediate (CI) and secondary ozonide (SOZ) of DMB, ...

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