Reduction of alkoxysilanes, halo-silanes and-Germanes with lithium aluminium hydride under phase-transfer conditions

VN Gevorgyan, LM Ignatovich, E Lukevics

Index: Gevorgyan, V. N.; Ignatovich, L. M.; Lukevics, E. Journal of Organometallic Chemistry, 1985 , vol. 284, p. C31 - C32

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Citation Number: 21

Abstract

In the presence of phase-transfer catalysts, silicon and germanium organo- hydrides were obtained in high yield by reduction of the corresponding halo and alkoxy derivatives with lithium aluminium hydride in the solid LiA1H4/ hydrocarbon two-phase system. ... The preparation of highly reactive hydro-silanes and -germanes by reduction of various silicon- and germanium-functional ... SYNTHESIS OF ORGANO-SILANES AND -GERMANES IN THE SOLID LiAlH,/HYDROCARBON ...