Crystal structure of a dewar benzene derivative formed from fluoro (triisopropylsilyl) acetylene

T Hanamoto, Y Koga, T Kawanami…

Index: Hanamoto, Takeshi; Koga, Yukinori; Kawanami, Toshio; Furuno, Hiroshi; Inanaga, Junji Angewandte Chemie - International Edition, 2004 , vol. 43, # 27 p. 3582 - 3584

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Citation Number: 18

Abstract

Halogenoacetylenes are probably one of the most intriguing classes of acetylene compounds. Although some synthetic routes to 1-haloacetylenes have been reported, there are very few reports on the syntheses of 1-fluoroacetylenes.[1] In 1959, the first synthesis of 1-fluoroacetylene itself was accomplished by Middleton and Sharkey, who used pyrolysis of fluoromaleic anhydride.[2] Five years later Viehe and et al. reported the synthesis of tert- ...