Tin for organic synthesis. Part 15: The use of 1, 2-bis (trimethylstannyl)-1-alkenes in electrophilic destannylation reactions

M Niestroj, WP Neumann, TN Mitchell

Index: Niestroj, Michael; Neumann, Wilhelm P.; Mitchell, Terence N. Journal of Organometallic Chemistry, 1996 , vol. 519, # 1-2 p. 45 - 68

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Citation Number: 21

Abstract

Z-1, 2-Bis (trimethylstannyl)-1-alkenes show different types of reaction behaviour towards various electrophiles. p-Tolysulphonyliso-cyanate forms five-membered tin-nitrogen- containing heterocycles. 1, 1-Dichloromethylmethyl ether reacts with carbofunctionalised distannylalkenes to yield α, β-unsaturated aldehydes, which are useful tools for the synthesis of further substituted vinylstannanes. Z-1, 2-Bis (trimethylstannyl)-1-alkenes ...