Trigonal-bipyramidal five-coordinate trisolefin complexes of platinum (II)

L Mink, MF Rettig, RM Wing

Index: Mink, Larry; Rettig, Michael F.; Wing, Richard M. Journal of the American Chemical Society, 1991 , vol. 113, # 6 p. 2065 - 2071

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Citation Number: 12

Abstract

The compound is nonconducting in CDCI3. Growth of Single Crystals of 1. Zeise's dimer (I41. I mg, 0.24 mmol) was reacted with DMBN (71.04 mg, 0.48 mmol) in 4.5 mL of CDCI,. The reaction mixture was stirred for 2 min and the solvent concentrated to 0.5 mL under reduced pressure. A IO-fold amount of hexane (5 mL) was added and the solution was concentrated under vacuum until solid started to form. The solution was then stored at-24 “ ...