An efficient electrochemical route to (perfluoroalkyl) alkynes

P Calas, P Moreau, A Commeyras

Index: Calas, Patrick; Moreau, Patrice; Commeyras, Auguste Journal of the Chemical Society, Chemical Communications, 1982 , # 8 p. 433 - 434

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Citation Number: 26

Abstract

Perfluorinated alkynes are potential intermediates for the introduction of perfluoroalkyl chains in organic compounds and have previously been prepared from the corresponding perfluoroalkyl iodides. The lower alkynes RF-CS-H (R, = CF3, C2F5, or i-C3F,) were the first reported,lS2 and their chemistry was later de~eloped.~ Long-chain homologues have been prepared more recently either from bromination, de- hydrobromination, and debromination reaction^,^ or from ...

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