Russian Journal of Applied Chemistry

A new electrochemical procedure for preparing 2, 4, 6-triphenylselenopyran from 1, 5-diketones under conditions of acid catalysis

TG Dmitrienko, SS Popova

Index: Dmitrienko; Popova Russian Journal of Applied Chemistry, 2008 , vol. 81, # 3 p. 448 - 451

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Abstract

Abstract A new electrochemical procedure was developed for preparing 2, 4, 6- triphenylselenopyran from 1, 5-diketones under conditions of acid catalysis at oxidative electrochemical activation of hydrogen selenide in the presence of a one-electron oxidizing agent in a nonaqueous solution. The electrolysis products were analyzed by gas chromatography with a mass-selective detector.